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jenn...
i love the book "UNDERSTANDING EXPOSURE" by bryan peterson. it explains the fstops, shutter speeds and how they work together and why you'd choose certain combinations in certain situations...there are several ways to get a correct exposure in any situation but there are reasons we choose certain combinations...for example to blur the background or alternatively to keep as much of it in focus as possible.
i'd start there.
then, "DIGITAL PHOTOGRAPHY" by scott kelby is a great read.
as for time of day, not the middle of the day. in our area this time of year, i'd say before 10a and after 3:30p...on the far end of those ranges would be best.
during the middle of the day you can try to find "open shade" like under a covered porch, for example...where the light is great but not harsh. or, sometimes under a large tree...but that dapples the light IME so not always so easy to find a good spot.
hth...
i'd also suggest taking notes on your exposure number, fstop, sspeed and lighting so you can learn from your mistakes...i learned that way on film when i was 16. it's a much faster learning curve on digital...
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